No, there is not. This is actually considered as an error, explained below.
In this case, where you want to redirect www to a completely different site, you'd remove both the CNAME and the A and replace it with another record of either the type A or CNAME, but not both.
Also notice that CNAME works merely as an alias for the canonical name. It won't perform any actual redirection, as redirection is a function of the HTTP protocol, instead of DNS.
If a hostname has a CNAME record, it must not have other resource records of other type. References:
RFC 1912, 2.4 CNAME records
A CNAME record is not allowed to coexist with any other data. In
other words, if suzy.podunk.xx is an alias for sue.podunk.xx, you can't also have an MX record for suzy.podunk.edu, or an A record, or even a TXT record. Especially do not try to combine CNAMEs and NS records
If you use a CNAME, the DNS server should return both CNAME record and the A record for the canonical hostname it's pointing to. The same applies to IPv6 AAAA records.
RFC 1034, 3.6.2 Aliases and canonical names
For example, suppose a name server was processing a query with for
USC-ISIC.ARPA, asking for type A information, and had the following
resource records:
USC-ISIC.ARPA IN CNAME C.ISI.EDU
C.ISI.EDU IN A 10.0.0.52
Both of these RRs would be returned in the response to the type A
query, while a type CNAME or * query should return just the CNAME.
The only exception is DNSSEC.
RFC 2181, 10.1 allowed SIG, NXT, and KEY records, while the currently used definition is:
RFC 4035, 2.5 Changes to the CNAME Resource Record
If a CNAME RRset is present at a name in a signed zone, appropriate
RRSIG and NSEC RRsets are REQUIRED at that name. A KEY RRset at that
name for secure dynamic update purposes is also allowed ([RFC3007]).
Other types MUST NOT be present at that name.
This is a modification to the original CNAME definition given in
[RFC1034]. The original definition of the CNAME RR did not allow any
other types to coexist with a CNAME record, but a signed zone requires
NSEC and RRSIG RRs for every authoritative name. To resolve this
conflict, this specification modifies the definition of the CNAME
resource record to allow it to coexist with NSEC and RRSIG RRs.