PostgreSQL uses locales from either the C library or the ICU library. If you want to use C library locales, as your question suggests, you can look at
SELECT collname FROM pg_collation WHERE collprovider = 'c';
for the available collations. If the one you are looking for is missing, you'll have to create it on the operating system:
for Redhat-based Linux distributions, install the glibc-all-langpacks package
for Debian-based Linux distributions, generate the locale with
locale-gen en_AU.utf8
Once you have the locale on the operating system, restart the PostgreSQL server and import the new locales into the system catalog with
SELECT pg_import_system_collations('pg_catalog');
I recommend using ICU collations, particularly from v15 on, where you can use ICU as default locale provider.