Typically the maximum stress for a thin walled spherical pressure vessel for a given diameter, thickness and pressure is:
$$\sigma = \frac{P\cdot R}{2\cdot t}$$
where:
- $\sigma$ is the observed pressure (in Pa)
- $P$ is the pressure (in Pa)
- $R$ is the radius of the vessel (in m)
- $t$ : is the thickness of the vessel (in m)
using this it is possible to find the minimum mass of a pressure vessel is (Wikipedia)
$$M={3 \over 2}PV{\rho \over \sigma }$$,
where:
- M is mass, (kg)
- P is the pressure difference from ambient (the gauge pressure), (Pa) (100000Pa = 1 Atm)
- V is volume,
- $\rho$ is the density of the pressure vessel material, (expressed in $kg/m^3$)
- $\sigma_{all}$ is the maximum allowable working stress that material can tolerate. ($Pa$)
However, an interesting parameter in the question which is without changing much its shape. That can be interpreted as having a very small deformation. Usually a common value which is used to denote small deformation within the elastic range is 0.2% or (0.002). So the value that you could use for the allowable stress is $\sigma_{all}= E\cdot 0.002 = 181 GPa \cdot 0.002= 362 MPa$
Compression buckling
An very important additional check is that of buckling (because the shell will be under compressive loads).
The buckling pressure $q_C$ of a elastic thin spherical shell was obtained by Zoelly (1915) and Van der Neut (1932):
$$q_c = \frac{2 E}{[3(1-\nu^2)]^{1/2}} \left(\frac{h}{R}\right)^2 \tag{eq:2}$$
where
- E is the elastic modulus
- $\nu$ is the Poisson Ratio
- $h$ is the shell thickness
- $R$ is the shell radius. Assuming a volume V, the radius of the sphere will be
$R= \sqrt[3]{\frac{3V}{4\pi}}$
Therefore, given that the critical pressure needs to be 1 atm ($q_C= 1Atm = 100000Pa$), the minimum thickness can be estimated:
$$q_c = \frac{2 E}{[3(1-\nu^2)]^{1/2}} \left(\frac{h}{R}\right)^2 \tag{eq:2}$$
$$ h = \sqrt[3]{\frac{3V}{4\pi}} \sqrt{\frac{q_c}{2 E}\sqrt{3(1-\nu^2)}} $$
After having calculated the minimum thickness, it is possible to obtain the total required volume of material $V_m$ and weight $M$ by:
$$V_m = 4\pi R^2 h $$
$$M = V_m\cdot \rho = 4\pi R^2 h \cdot \rho $$